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In physical chemistry, the Faraday constant (symbol , sometimes stylized as ℱ) is a physical constant defined as the quotient of the total () by the amount () of elementary charge carriers in any given sample of matter: it is expressed in units of per mole (C/mol). As such, it represents the " elementary charge", that is, the electric charge of one mole of elementary carriers (e.g., protons). It is named after the English . Since the 2019 revision of the SI, the Faraday constant has an exactly defined value, the product of the elementary charge (, in coulombs) and the Avogadro constant (, in reciprocal moles):


Derivation
The Faraday constant can be thought of as the proportionality factor between the charge in (used in physics and in practical electrical measurements) and the amount of substance in moles (used in chemistry), and is therefore of particular use in , particularly in calculations. Because the elementary charge is exactly , and there are exactly entities per mole, the Faraday constant is given by the product of these two quantities:

The value of was first determined in the 1800s by weighing the amount of deposited in an electrochemical reaction, in which a measured current was passed for a measured time, and using Faraday's law of electrolysis. NIST Introduction to physical constants Until about 1970, the most reliable value of the Faraday constant was determined by a related method of electro-dissolving silver metal in .


Other common units
  • 96.485 kJ per volt–gram-equivalent
  • 23.061 kcal per volt–gram-equivalent
  • 26.801 A·h/mol


Faraday – a unit of charge
Related to the Faraday constant is the "faraday", a unit of electrical charge. Its use is much less common than of the , but is sometimes used in electrochemistry. Foundations of Physics, Volume 2, by R. S. Gambhir, 1993, p. 51 One faraday of charge is the charge of one mole of elementary charges (or of negative one mole of electrons), that is,
1 faraday =  F × 1 mol =  = .

Conversely, the Faraday constant F equals 1 faraday per mole.

The faraday is not to be confused with the , an unrelated unit of ().


See also
  • , the unit of electrical capacitance
  • Faraday efficiency
  • Faraday's laws of electrolysis

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